The highest number of one-move mates that I have found is currently 91. It is based off of the following idea:
RB.....K
........
......Q.
........
........
........
........
........
Here, each dot or letter represents a square on the board. There are 7 positions that the bishop can move to, so I would count this as 7 different moves that end in check mate, ie. 7 different 1 move mates. When counting the total number of moves that mate from each piece in the board, I will represent it like this:
07.....K
........
......0.
........
........
........
........
........
I found the following board based off of this idea that has a total of 91 different moves which result in checkmate:
B..RQ.BQ
Q....R..
..RB....
RB.K.B.Q
Q......Q
.R......
B..B..R.
Q..QQQQB
Where many pieces have several possible mates (a=10, b=11):
0..03.02
2....8..
..7b....
03.K.a.1
3......3
.a......
0..7..9.
2..13220
There might be a small permutation of this board which increases in incrementally, but I am interested in what other ideas people have from scratch.