TL;DR
The first player should decrease $M_1$, $M_{96}$, $M_{97}$, $M_{98}$, $M_{99}$ in the first move. Afterwards he can repeat all moves of the second player to win.
This is guaranteed to work because the numbers $M_1 .. M_{95}$ are all even after the first move, and each of the numbers $M_{96} .. M_{99}$ is bigger than the sum of all numbers $M_1 .. M_{95}$. At the end all numbers $M_1 .. M_{95}$ will be $0$, and the numbers $M_{96} .. M_{99}$ will be positive with the second player to move.
The rest of the post describes how I came to the conclusion above.
Closer look
Let's make two groups of numbers $M_1 .. M_{95}$ and $M_{96} .. M_{99}$:
$\begin{array}{} M_1 & M_2 & M_3 & ... & M_{95} & \qquad\qquad & M_{96} & M_{97} & M_{98} & M_{99} \\ 1 & 2 & 4 & ... & 2^{94} & \qquad\qquad & 2^{95} & 2^{96} & 2^{97} & 2^{98} \end{array}$
The sum of the numbers $M_1 .. M_{95}$ is $2^{95}-1$ which is smaller than $M_{96}=2^{95}$. Even if we would decrease all numbers $M_{96} .. M_{99}$ in each move, they will stay positive until the end of the game.
Changing the rules
This allows us to create an equivalent game with slightly different rules. First we get rid of the numbers $M_{96} .. M_{99}$. Second we change the move rule to the following:
- In every move, the active player picks between one and five numbers and decreases each of them by $1$.
This game is equivalent to the original game, because we can decrease the missing one to four numbers from the group $M_{96} .. M_{99}$ without changing the outcome of the game.
Winning position
Let us assume we have a position where all numbers are even numbers. In such a position it is always possible to repeat the move done by the previous player reaching again a position where all numbers are even numbers. At some point the first player will run out of possible moves and the second player wins.
How to win?
The first player can decrease the number $M_1=1$ (and $M_{96} .. M_{99}$ in the original game) and reach the winning position from the previous chapter (he will be then the second player).