Suppose the first digit is a and the last digit is c. (The rest of the number can be denoted as b.)
Then our original number is $a\cdot 10^{n-1}+b\cdot 10 + c$ and after swapping the digits it is $c\cdot 10^{n-1}+b\cdot 10 + a$.
The question asks whether there are $a,b,c$ such that $\frac{c\cdot 10^{n-1}+b\cdot 10 + a}{a\cdot 10^{n-1}+b\cdot 10 + c} = N$ for some integer $N > 1$. Clearly $N < 10$ as they have the same number of digits as well. Also, $c > a$.
Subtracting one from the above equation, we get $\frac{(10^{n-1}-1)(c-a)}{a\cdot 10^{n-1}+b\cdot 10 + c} = N-1$, i.e. $\frac{(10^{n-1}-1)(c-a)}{N-1} = a\cdot 10^{n-1}+b\cdot 10 + c$.
Now we proceed via casework:
We have the bounds that $N-1 \in \{1,2,3,4,5,6,7,8\}$.
If $N-1 \in \{1,2,4,5,8\}$, then $10^{n-1}-1$ shares no factors with $N-1$ so if the LHS is an integer, it must be a factor of $10^{n-1}-1$. Since $a$ should be smaller than $c$, our options are: $19\dots98$, $29\dots97$, $39\dots96$, $49\dots95$, corresponding to $\frac{c-a}{N-1}$ values of $2,3,4,5$ but at the same time $c-a$ values of $7,5,3,1$. At no point are the right numbers a multiple of the left numbers, so this rules out this possibility.
If $N-1 \in \{3,6\}$, then $10^{n-1}-1$ could absorb a factor of $3$. This gives our options as $13\dots32$, $16\dots65$, $19\dots98$, $26\dots64$, $29\dots97$, corresponding to $\frac{3(c-a)}{N-1}$ values of $4,5,6,8,9$ and $c-a$ values of $1,4,7,2,5$. But similarly, the right hand numbers are never a multiple of the left hand numbers.
If $N-1 = 7$, then $10^{n-1}-1$ could absorb a factor of $7$. We're pretty restricted in this case - $(c-a)$ must be $8$, because otherwise the LHS has $n-1$ digits versus the RHS $n$ digits. $7|10^{n-1}-1$ only when $6|n-1$ for which the result is $142857\dots142857$. Adding $9\dots9$ to this, we get $1142857\dots142856$, which has $c-a$ value of $5$, which is not $8$. So this concludes our casework and therefore there are no solutions.