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added 99 characters in body
hexomino
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Partial answer

1. Far north Silicon Valley's research & development leaders surround Jessica (8)

Svalbard - Alba inside S.V.R & D

2. Pop star loses British-American distribution rights to music organization (4)

Sony?

4. Clapton song loses heart, gets inside club to be McCartney song (6)

Lalula = La(y)la + club

5. Yale professor Jenny with rights to Diablo north of Mali's capital (8)

Lindblom - Lind + blo + M

6. In retrospect, Korean Secretary-General is a Swedish actress (5)

Noomi - The end of Ban Ki-moon spelled backwards

8. Excess of vitamins lacking irate vim leads to state of trance (8)

Hypnosis - Hypervitaminosis without irate vim

9. Metric cruise around psychic medium is funny business (6)

Sitcom?

18. Ethiopian opera featuring keyboard instrument (5)

Piano - Ethiopian opera

22. Standards organization backs network model (3)

ISO - OSI backwards

23. Boating tool from metallic mineral, reportedly (3)

Oar - sounds like ore

24. 113 previously used underwater turtle heads (3)

Uut - used underwater turtle

28. Don't start to hide behind blue-green toxin (7)

Cyanide = Cyan + (h)ide

36. Spice rings encircle half-hearted Ronald (7)

Oregano = O + regan + o

38. Deep blue crowdfunding site with no ego (6)

Indigo = Indiegogo - ego

41. Back balsam? Ah, a beautiful country (7)

Bahamas - balsam? Ah, a beautiful

44. On the premises, part spins it up (2 4)

In situ - spins it up

47. Māori prophet's revolutionary aura (3)

Rua

50. Vengeful seaman held in Allahabad (4)

Ahab - Allahabad

51. Cold sea fog from an empty hangar (4)

Haar - ha(ng)ar

60. Motor club's credit rating (3)

AAA

61. Brush a pet in living room (5)

Groom - living room

62. Elevated bonus card game (3)

Uno - bonus

63. Gorilla secretly escapes (3)

Ape - escapes

64. Empty spaces for Roombas (7)

Vacuums - although vacua is usually the plural

69. Melted into Braxton (4)

Toni - anagram of into

hexomino
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