8
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My prefix is not single
My infix is cold to hold
My postfix can mean my whole
I’m clean when I’m on the road

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9
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My guess is

BICYCLE

My prefix is not single

The prefix bi- means "two", so not single.

My infix is cold to hold

Icy means extremely cold.

My postfix can mean my whole

Cycle is a synonym for bicycle.

I’m clean when I’m on the road

The bicycle is a clean way of transportation.

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