Begin by assuming the height of the rectangle is $1$ and the width is $1+x$.
You can then observe that there could be a rectangle between the upper right corner of the big rectangle and the peak of the smaller arc that has the same height to width ratio of the larger one.
This smaller rectangle will then have a height of $1-x$ and a width of $x$, and we can relate the two by the equality $\frac{1}{1+x} = \frac{1-x}{x}$, which can be re-formatted to: $0=\frac{1-x-x^2}{x}$
we then need to find the roots of this equation to solve for x. If x is 0, we get infinity so there's no need to consider that possibility, and we can simplify to $0=1-x-x^2$. For this we can use the quadratic formula to solve for x: $-\frac{1±\sqrt{5}}{2}$, which yields -1.618 and .618 (woot for golden ratio :D)
Obviously a negative value for x does not make sense, so we take $x=.618$. Moving to trig for a moment we can find the angle measure in question now knowing the side lengths of the larger rectangle to be $1$ and $1+.618$. This makes the expression to solve the question: $arctan(\frac{1+.618}{1})$ or: $arctan(φ)$ which is equal to 1.01722197 rad
I'm not sure if I can eliminate trig all together to get a proper angle measure out of this one. Maybe it's a common ratio I'm supposed to remember like the 30-60-90 triangle?