As Rubio points out, the question is slightly ambiguous.
If we assume that a player spins the cylinder on each turn, then
In round 1, Player 1 dies with probability $\frac13$.
So there is a $\frac23$ probability of there being a round 2.
Then, Player 2 dies with probability $\frac13$.
Thus, the absolute probability of Player 2 dying in round 2
is $\frac23\times\frac13$,
following the rule that the probability of event A happening,
and then event B, is
$$P(A)\times P(B\text{, given that }A\text{ has happened})$$
For example, in this pinball machine
(where the ball is dropped in at the top,
and takes branches with equal probability):
the probability that the ball will go down the leftmost chute
is $\frac{1}{10}$ —
because $P(A)$, taking the left branch at the upper fork, is $\frac12$,
and $P(B\text{ given }A)$,
taking the leftmost branch at the lower division point, is $\frac15$.
And so it goes: the probability of Player 1 dying in round 3
is $\left(\frac23\right)^2\times\frac13$
because this requires Player 1 to survive the first round ($\frac23$),
Player 2 to survive the second round ($\frac23$),
and Player 1 to run out of luck in round 3 ($\frac13$).
Similarly,
the probability of Player 2 dying in round 4
is $\left(\frac23\right)^3\times\frac13$, etc.
(If it helps you to understand the exponential factor,
consider flipping a fair coin ten times in a row.
Most people find it “obvious” that the probability
of getting heads 10 times in a row is $\big(\frac12\big)^{10}$.)
Thus, the total probability of Player 1 dying is
\begin{align}\qquad\qquad P_1&=\frac13~~+~~~\left(\frac23\right)^2\,\times\frac13~~+~~\left(\frac23\right)^4\times\frac13~~+~~\dots~\end{align}
Solving this is simple algebra:
\begin{align}P_1&=\frac13~~+~~\,\left(\frac23\right)^2\,\times\frac13~~+~~\left(\frac23\right)^4\times\frac13~~+~~\dots\\[1ex]&=\frac13~~+~~\left(\frac49\right)\phantom{^1}\times\frac13~~+~~\left(\frac49\right)^2\times\frac13~~+~~\dots\\[1ex]-\qquad\frac49~P_1&=\phantom{\frac13~~+~~}\left(\frac49\right)\phantom{^1}\times\frac13~~+~~\left(\frac49\right)^2\times\frac13~~+~~\dots\\[1ex]\hline\frac59~P_1&=\frac13\\[2ex]P_1&={\frac13\over\frac59}~~=~~\frac13\times\frac95~~=~~\frac{9}{15}=\frac35~~=~~0.6\end{align}
Another way of getting to the same result is to note that
\begin{align}P_2&=\left(\frac23\right)\times\frac13~~+~~\left(\frac23\right)^3\times\frac13~~+~~\left(\frac23\right)^5\times\frac13~~+~~\dots\end{align}
and then note that $P_2=\frac23P_1$.
But $P_1+P_2=1$, so $P_1+\frac23P_1=\frac53P_1=1$, so $P_1=\frac35$.
t be first if it
s rotating $\endgroup$