The solution can easily be obtained using a truth-table.
Let's symbolize using the following atomic sentences:
M: Marcus stole the jewels
L: Leon stole the jewels
S: Sylvester stole the jewels
Assuming "Marcus and Sylvester were at the bar together when the jewels were taken" implies that that neither of them stole the jewels, the relevant assertions of Frank, Marcus, Leon, and Sylvester become:
Frank: ~M
Marcus: ~L
Leon: ~M & ~S
Sylvester: L
where '~' represents negation and '&' represent conjunction.
We can now look at all possible assigments of Truth and Falsity to the atomic sentences and how these assignments affect the possible truth-values of the complex sentences asserted by Frank, Marcus, Leon, and Sylvester:
Because only one person can be telling the truth (ex hypothesi), we want to look at rows where only one of Frank, Marcus, Leon, or Sylvester says something true. Rows 1, 2, 5, and 6 are the only such rows.
That there are multiple rows indicates that your question is poorly constrained: There are multiple circumstances consistent with only one person telling the truth and in which possibly multiple people steal the jewels.
In case one, Sylvester is telling the truth that Leon stole the jewels, and in fact, Leon, Marcus, and Sylvester all stole the jewels.
In case two, Marcus is telling the truth that Leon did not steal the jewels, and in fact Marcus and Sylvester both stole the jewels.
In case five, Sylvester is telling the truth that Leon stole the jewels, and in fact Leon and Marcus both stole the jewels.
In case 6, Marcus is telling the truth that Leon didn't steal the jewels, and in fact only Marcus stole the jewels.
If we assume that the jewels were stolen by only one person, case 6 is the only option.
If we assume that Leon's statement that "Marcus and Sylvester were at the bar together when the jewels were taken" says nothing about whether or not they stole the jewels, we end up with the following truth-table:
where Q stands for Leon's irrelevant statement. In such a situation, only cases 5 and 6 are ones in which a single person is telling the truth.
In case 5, Sylvester is telling the truth that Leon stole the jewels, and in fact Leon and Marcus both stole the jewels.
In case 6, Marcus is telling the truth that Leon did not steal the jewels, and in fact only Marcus stole the jewels.
You will notice that Marcus steals the jewels in every one of these possible scenarios, although he is not necessarily the only one!