Let the vertices of the rectangle be $(0,0), (a,0), (0,b)$, and $(a,b)$.
The positive-slope diagonal line is $y = (\frac{b}{a})x$. The negative-slope line meets the boundary of the rectangle at vertex $(a,0)$, and also at some point $(c,b)$. The equation of this line is $y = \left(\frac{b}{c-a} \right)(x-a)$.
We calculate that the intersection point of the two lines is $(x,y) = \left( \frac{a^2}{2a-c}, \frac{ab}{2a-c} \right)$.
Now, the area of the smaller triangle is $2$, so
\begin{eqnarray}2& =& \left(\frac{1}{2}\right)(a-c)(b-y)\\4(c-2a) &=& (a-c)b(c-2a) + (a-c)ab\phantom{***}(*)\end{eqnarray}
On the other hand, consider the triangle with area $2+3 = 5$:
$5 = \left( \frac{1}{2} \right) b(a-c)$,
so
$b = 10/(a-c)$.
Substituting into equation $(*)$, we get
\begin{eqnarray*}4(c-2a) &=& 10(c-2a) + 10a\\a &=& 3c\end{eqnarray*}
and therefore
$b = 5/c$.
At this point we see that
$Area(rectangle) = ab = (3c)(5/c) = 15$
Thus
\begin{eqnarray*}Area(?) &= &15 - 2 - 3 - \left( \frac{1}{2} \right)ay\\&=& 10 - \left( \frac{1}{2} \right) \left(\frac{a^2b}{2a-c}\right)\\&=& 10 - \left( \frac{1}{2} \right) \left(\frac{(9c^2)(5/c)}{6c-c}\right)\\&=& 10 - \frac{9}{2}\\& =& \frac{11}{2}.\end{eqnarray*}