This is similar to what daw tries to do (as I understand it) but I hope I can explain the idea better and produce a better coverage at the same time.
Alice will use the following basic shape
.#..
###.
.###
..#.
and arrange lots of pieces like that in a pattern so that the don't touch each other. She doesn't have to lie a complete basic shape in one move, she just fills in spots that ought to be tiled in the large pattern.
.#.###.
###.#.#
.###.##
#.#.#.#
##.###.
The empty spots form infinite lines along some diagonals and in between you can always fit exactly one piece.
A little bit of counting now shows that
We need 4 empty fields for each 8 filled fields, giving us a coverage of 8/12=2/3
of the total area. In each turn Alice adds 10 new pieces and Bob can remove at most
8
So in the long run Alice can cover arbitrarily large parts of the plane with this pattern.