Disappointing result, but hopefully interesting.
This solution is a fractal.
The first three iterations are pictured at the top, and the 'rewrite rule' is at the bottom.

Points shown are approximate; Alice should place her points infinitesimally close to these ideal points, whilst ensuring that the depicted circles are a valid and optimal selection for Bob.
Alice can iterate this fractal as many times as desired, and can place points as close to the ideal points as desired, meaning that Alice can make her share arbitrarily close to that of the limit of the fractal.
Bob's area can be calculated as follows:
In the rewrite rule, there are four black circles of radius $\frac{1}{3}$, and four of radius $\frac{1}{6}$, for a total black area of $$k=4\cdot((\frac{1}{3})^2+(\frac{1}{6})^2)\cdot\pi=\frac{5}{9}\pi$$
There are also four blue circles of radius $\frac{1}{2}$, for a total blue area of $$b=4\cdot(\frac{1}{2})^2\cdot\pi=\pi$$
Thus, the percentage area of the rewrite rule covered when expanded infinitely, is $$r=\frac{k+br}{2\cdot\pi}$$ $$r\cdot(1-\frac{b}{2\pi})=\frac{k}{2\pi}$$ $$r\cdot(1-\frac{1}{2})=\frac{5}{18}$$ $$r\cdot\frac{1}{2}=\frac{5}{18}$$ $$r=\frac{5}{9}$$
We can use this to calculate the area covered by the whole fractal.
In the initial state, there are two black circles of radius $\frac{1}{3}$ and two blue circles of radius $\frac{1}{2}$, giving a total area of $$a=\frac{2\cdot(\frac{1}{3})^2\cdot\pi+2\cdot(\frac{1}{2})^2\cdot\pi\cdot r}{\pi}=\frac{2}{9}+\frac{1}{2}\cdot r=\frac{2}{9}+\frac{1}{2}\cdot\frac{5}{9}=\frac{1}{2}$$
So, Alice can make her portion of the circle arbitrarily close to
50%. She's probably better off placing just the two points like in @I'm Nobody's answer.
However, the fact that this random fractal satisfying the constraints ends up having an area of $\frac{1}{2}$ lends additional credence to that being the maximum.