The solution is
Sudoku
My early part is very clean, Use it to obtain a sheen.
As mentioned before, "sud" or soap sud is a kind of lye or dissolved base chemical (something to do with metal hydroxide? can't be arsed to go deeper into chemistry though). From what I understand this is the base chemical used to make soap.
From search enginges you get Sud = "froth made from soap and water" and thus can be used to create soap and "obtain a sheen" or in other words clean things.
My middle part is just a verb, Very common, needs no blurb.
"do" is a very common verb. One could say it doesn't need a blurb. For the sake of rhyming? ;)
My final part is. Too right, is! You think that's cryptic, well it is.
The cryptic clue here is about alphanumerics. "Too right" can be interpreted as +2. So from "I S" we get "K U".
My whole all over PSE arises, In all different shapes and sizes.
All together we get SUD + DO + KU = SUDOKU, a type of puzzle that can be founds all over PSE in all shapes and sizes. The solution can be confirmed using the last clue.